- Dangerous Goods List and limited quantities exceptions

IMDG CODE (Amdt, 33-06)

Part 3 - Dangerous Goods List and limited quantities exceptions

Portable tanks and bulk containers EmS

IMO UN Provisions

tank tank instructions instructions

(12) (13) (14) (15)

F-8, S-X F-8, S-X F-8, S-X F-8, S-X F-8, S-X F-8, S-X F-8, S-X F-8, S-X F-8, S-X F-8, S-X F-8, S-X F-8, S-Y F-8, S-Y F-8, S-Y F-8, S-Y F-8, S-Y F-8, S-Y F-8, S-Y F-8, S-Y F-8, S-Y F-8, S-Y F-8, S-Y

F-8, S-Y

F-8, S-Y F-8, S-X F-8, S-X F-8, S-X F-8, S-Y

IMDG CODE (Amdt. 33-06)

Stowage and segregation

(16) Category 07 Category 07 Category 07 Category 08 Category 07 Category 07 Category 07 Category 08 Category 07 Category 06 Category 08 Category 12 Category 10 Category 10 Category 08 Category 10 Category 08 Category 09 Category 09 Category 05 Category 10 Category 10

Category 10

Category 08 Category 07 Category 07 Category 03 Category 10

Chapter 3.2 - Dangerous Goods List

Properties and observations

(17)

UN No.

(18) 0462 0463 0464 0465 0466 0467 0468 0469 0470 0471 0472 0473 0474 0475 0476 0477 0478 0479 0480 0481 0482 Substance. Mass detonating explosive which will become 0483 more sensitive if the wetting or desensitizing agents are lost.

Substance. Mass detonating explosive which will become 0484 more sensitive if the wetting or desensitizing agents are lost.

0485 See glossary of terms in appendix B for "ARTICLES, 0486 EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES, EEl)".

See glossary of terms in appendix B for "SIGNALS, SMOKE". 0487 See glossary of terms in appendix B for "AMMUNITION, 0488 PROOF".

Substance. 0489

40 Part 3 - Dangerous Goods List and limited quantities exceptions

-~~-~-~---... ---~~~-~---~".---... -.-.... --.. -.

UN Proper Shipping Name

No. (PSN)

(1) (2)

0490 NITROTRIAZOLONE (NTO)

0491 CHARGES,PROPELUNG

0492 SIGNALS, RAILWAY TRACK, EXPLOSIVE

0493 SIGNALS, RAILWAY TRACK, EXPLOSIVE

0494 JET PERFORATING GUNS, CHARGED oil well, without detonator

0495 PROPELLANT, UQUID

0496 OCTONAL

0497 PROPELLANT, UQUID

0498 PROPELLANT, SOUD

0499 PROPELLANT, SOUD

0500 DETONATOR ASSEMBUES, NON-ELECTRIC for blasting

0501 PROPELLANT, SOUD

0502 ROCKETS with inert head

0503 AIR BAG INFLATORS or AIR BAG MODULES or SEAT-BELT PRETENSIONERS 0504 1H-TETRAZOLE

1001 ACETYLENE, DISSOLVED

1002 AIR, COMPRESSED 1003 AIR, REFRIGERATED LIQUID

41

Class or divi-sion (3) 1.10

1.4C

1.3G

1.4G

1.40

1.3C

1.10

1.1C

1.3C

1.48

1.4C

1.2C

1.4G

1.10 2.1

2.2 2.2

Subsidiary risk(s)

(4)

5.1

... ---.--~~--~~~-~~-.--- ----- -

---Packing Special Limited Packing IBC

group provisions quantities

Instruc- Provisions Instruc- Provisions

tions tions

(5) (6) (7) (8) (9) (10) (11)

None P112 (b) or (e)

None P143 PP76

None P135

None P101

224 None P115 PP53

PP54 PP57 PP58 None P112 (b)

or (e)

224 None P115 PP53

PP54 PP57 PP58 None P114 (b)

None P114 (b)

None P131

None P114 (b)

None P130 PP67

LP101 L1

235 None P135

289

None P112 (e) PP48

None P200

292 120 mi P200

None P203

IMDG CODE (Amdt. 33-06)

Chapter 3.2 - Dangerous Goods List

-~~~-

---~~-"-Portable tanks and bulk containers EmS Stowage and segregation Properties and observations UN

IMO

UN

Provisions No.

tank tank instructions instructions

(12) (t3) (14) (15) (16) (17) (18)

F-B. S-Y Category 10 Substance. 0490

F-B, S-X Category 06 See glossary of terms in appendix B for "CHARGES, 0491 PROPELLING".

F-B, S-X Category 07 See glossary of terms in appendix B for "SIGNALS. RAILWAY 0492 TRACK, EXPLOSIVE".

F-B, S-X Category 06 See glossary of terms in appendix B for "SIGNALS, RAILWAY 0493 TRACK, EXPLOSIVE".

F-B, S-X Category 06 Articles consisting of a steel tube or metallic strip containing 0494 shaped charges connected by detonating cord, without means of initiation.

F-B, S-Y Category 10 Substances consisting of a deflagrating liquid explosive used 0495 for propulsion.

F-B, S-Y Category 10 Substance. Mixtures of mass detonating explosives. 0496

F-B, S-Y Category 10 Substances consisting of a deflagrating liquid explosive used 0497 for propulsion

F-B, S-Y Category 13 for on deck Substances consisting of a deflagrating solid explosive used 0498 stowage non-metallic liner for propulsion.

necessary if not in sealed sift-proof packages. Category 10 when in effectively sealed, sift-proof packages. For containers non-metallic lining is

necessary.

F-8, S-Y Category 13 for on-deck Substances consisting of a deflagrating solid explosive used 0499 stowage non-metallic liner for propulsion.

necessary if not in sealed sift-proof packages; or Category 10 when in effectively sealed, sift-proof packages. For containers non-metallic lining is necessary.

F-B, S-X Category 05 See glossary of terms in appendix B for "DETONATOR 0500 ASSEMBLIES, NON-ELECTRIC for blasting".

F-B, S-X Category 09 Substances consisting of a detonating solid used for 0501 propulsion.

F-B, S-X Category 03 See glossary of terms in appendix B for "ROCKETS with inert 0502 head".

F-B, S-X Category 02 See glossary of terms in appendix B for "AIR BAG INFLATORS 0503 or AIR BAG MODULES or SEAT-BELT PRETENSIONERS".

F-B, S-Y Category 10 Substance. 0504

F-D, S-U Category D. Shade from Flammable gas with slight odour. Explosive limits: 2.1 % to 1001 radiant heat. Clear of living 80%. Lighter than air (0.907). Rough handling and exposure to quarters. "Separated from" local heating should be avoided, since these conditions may chlorine. result in delayed explosion. Empty cylinders should be carried

with the same precautions as filled cylinders.

F-C, S-V Category A. Non-flammable gas. 1002

T75 TP5 F-C, S-W Category D. Liquefied, non-flammable gas. Strong oxidizing agent. 1003

TP22 Mixtures of liquid air with combustible materials or oils may

explode. May ignite organic materials.

IMDG CODE

(Amdt. 33-06)

41 - Dangerous Goods List and limited quantities exceptions

-... - . ~~~ ----

---~-UN Proper Shipping Name

No. (PSN)

(1) (2)

1005 AMMONIA, ANHYDROUS

1006 ARGON, COMPRESSED 1008 BORON TRIFLUORIDE

1009 BROMOTRIFLUOROMETHANE (REFRIGERANT GAS R 13Bl) 1010 BUTADIENES, STABILIZED or

BUTADIENES AND HYDROCARBON MIXTURE, STABILIZED with more than 40% butadienes

1011 BUTANE 1012 BUTYLENE 1013 CARBON DIOXIDE

1016 CARBON MONOXIDE, COMPRESSED 1017 CHLORINE

1018 CHLORODIFLUOROMETHANE (REFRIGERANT GAS R 22) 1020 CHLOROPENTAFLUOROETHANE

(REFRIGERANT GAS R 115) 1021

l-CHLORO-l,2,2,2-TETRAFLUOROETHANE (REFRIGERANT GAS R 124)

1022 CHLOROTRIFLUOROMETHANE (REFRIGERANT GAS R 13) 1023 COAL GAS, COMPRESSED 1026 CYANOGEN

1027 CYCLOPROPANE

1028 DICHLORODIFLUOROMETHANE (REFRIGERANT GAS R 12) 1029 DICHLOROFLUOROMETHANE

(REFRIGERANT GAS R 21)

1030 1,1-DIFLUOROETHANE (REFRIGERANT GAS R 152a)

1032 DIMETHYLAMINE, ANHYDROUS

1033 DIMETHYL ETHER 1035 ETHANE

42

Class or divi-sion (3) 2.3

2.2 2.3

2.2 2.1

2.1 2.1 22 2.3 2.3

2.2 2.2 2.2

2.2 2.3 2.3 2.1 2.2 2.2 2.1 2.1

2.1 2.1

.,- -

---.-~~-~-~---~---~--~.-Subsidiary Packing Special Limited Packing IBC

risk(s) group provisions quantities Instruc- Provisions Instruc- Provisions

lions lions

(4) (5) (6) (7) (8) (9) (10) (11 )

8 23 None P200

120

me

^P200

8 None P200

120

me

^P200

None P200

None P200 None P200 911 120 mfl P200

2.1 None P200

8 None P200

120 me P200 120

me

^P200

120 mfl P200

120 me P200

2.1 None P200

None P200 120 me P200 120 me P200 None P200 None P200

None P200 None P200

IMDG CODE (Amdt. 33-06)

Portable tanks and bulk containers EmS Stowage and segregation IMO UN Provisions

tank tank instructions instructions

(12) (13) (14)

TSO

TSO TSO

TSO TP19

TSO TSO TSO

TSO TSO TSO TSO TSO

TSO

(15) (16)

F-C, SoU Category

°

Clear of living quarters. "Separated from"

chlorine. "Separated from"

acids.

F-C, S-V Category A.

F-C, SoU Category O. Clear of living quarters.

F-C, S-V Category A.

F-O, SoU Category B. Clear of living quarters.

F-O, SoU Category E. Clear of living quarters.

F-C, S-V Category A.

F-O, SoU Category O. Clear of living quarters.

F-C, SoU Category O. Clear of living quarters.

F-C, S-V Category A.

F-O, SoU Category O. Clear of living quarters.

F-O, SoU Category E. Clear of living quarters.

F-C, S-V Category A.

F-O, SoU Category B. Clear of living quarters.

F-O, SoU Category

°

Clear of living quarters.

F-O, SoU Category B Clear of living quarters.

F-O, SoU Category E. Clear of living quarters.

~~-.-.--.---.----~~~~~~~~~~~

IMDG CODE (Amdt. 33-06)

Chapter 3.2 - Dangerous Goods List

Properties and observations

(17)

UN No.

(18) Liquefied, non-flammable, toxic and corrosive gas with a 1005 pungent odour. Lighter than air (0.6). Highly irritating to skin, eyes and mucous membranes. Suffocating in low

concentrations. Even though this substance has a flammability hazard, it only exhibits such hazard under extreme fire conditions in confined areas. Reacts violently with acids

Inert gas. Heavier than air (1.4). 1006

Non-flammable, toxic and corrosive gas Forms dense white 1008 corrosive fumes in moist air. Reacts violently with water,

evolving hydrogen fluoride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to glass and most metals. Much heavier than air (2.3S). Highly irritating to skin, eyes and mucous membranes.

Liquefied, non-flammable gas with a slight odour. Much 1009 heavier than air (5.2).

Liquefied, flammable gas with an unpleasant odour. Explosive 1010 limits: 2% to 12%. Heavier than air (1.84)

Flammable hydrocarbon gas. Explosive limits: 1.8% to 8.4%. 1011 Heavier than air (2.11 ).

Flammable hydrocarbon gas. Explosive limits: 1.6% to 10%. 1012 Heavier than air (2.0).

Liquefied, non-flammable gas. Heavier than air (l.S). Cannot 1013 remain in the liquid state above 31 "C.

Flammable, toxic, odourless gas. Explosive limits' 12% to 7S%. 1016 Slightly lighter than air (0.97).

Non-flammable, toxic and corrosive yellow gas with a pungent 1017 odour. Corrosive to glass and to most metals. Much heavier than air (2.4). Highly irritating to skin, eyes and mucous membranes.

Liquefied, non-flammable gas with a chloroform-like odour.

Much heavier than air (3.0).

Liquefied, non-flammable gas. Much heavier than air (S.4).

Liquefied, non-flammable gas. Much heavier than air (4.7).

Liquefied, non-flammable gas. Much heavier than air (3.6).

Cannot remain in the liquid state above 2goC.

Flammable, toxic gas. Explosive limits: 4.S% to 40%. Much lighter than air (0.4 to 0.6)

Liquefied, flammable, toxic gas with a pungent odour.

Explosive limits: 6.6% to 43%. Heavier than air (1.9).

Flammable hydrocarbon gas. Heavier than air.

Liquefied, non-flammable gas. Much heavier than air (4.2).

Liquefied, non-flammable gas with a chloroform-like odour.

Much heavier than air (3.6). Boiling point: 9'C.

1018 1020 1021

1022 1023 1026 1027 1028 1029 Flammable gas. Explosive limits: S% to 17%. Much heavier 1030 than air (2.3).

Liquefied, flammable gas with an ammonia-like odour. Heavier 1032 than air (1.6). Boiling point:

rc.

Suffocating in low

concentrations.

Flammable gas with a chloroform-like odour Heavier than air 1033 (1.6).

Flammable gas. Explosive limits: 3% to 16% Slightly heavier 1035 than air (1.0S).

42 Part 3 - Dangerous Goods List and limited quantities exceptions

--~---... -~~--- ^~^-~-~~- ^----~~~-- ^--~~--- ^~----~~~-.-~ -~--- ---~-~---- .---'._---- - ---.. -

---UN Proper Shipping Name Class Subsidiary Packing Special Limited Packing IBC

No. (PSN)

(1) (2)

1036 ETHYLAMINE

1037 ETHYL CHLORIDE

1038 ETHYLENE, REFRIGERATED LIQUID 1039 ETHYL METHYL ETHER

1040 ETHYLENE OXIDE or ETHYLENE OXIDE WITH NITROGEN up to a total pressure of 1 MPa (10 bar) at 50"C

1041 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 9% but not more than 87% ethylene oxide

1043 FERTILIZER AMMONIATING SOLUTION with free ammonia

1044 FIRE EXTINGUISHERS with compressed or liquefied gas

1045 FLUORINE, COMPRESSED

1046 HELIUM, COMPRESSED

1048 HYDROGEN BROMIDE, ANHYDROUS

1049 HYDROGEN, COMPRESSED

1050 HYDROGEN CHLORIDE, ANHYDROUS

1051 HYDROGEN CYANIDE, STABILIZED containing less than 3% water

1052 HYDROGEN FLUORIDE, ANHYDROUS

1053 HYDROGEN SULPHIDE 1055 ISOBUTYLENE

1056 KRYPTON,COMPRESSED 1057 LIGHTERS or LIGHTER REFILLS

containing flammable gas 1058 LIQUEFIED GASES non-flammable,

charged with nitrogen, carbon dioxide or air

43

or divi-sion (3) 2.1

2.1 2.1 21 2.3

2.1

2.2

2.3

2.2 2.3

2.1

2.3

6.1

2.3 2.1

22 21 2.2

risk(s)

(4)

2.1

51/8

6.1

group provisions

(5) (6)

912

225

201

quantities Instruc- Provisions Instruc- Provisions

tions tions

(7) (8) (9) (10) (11)

None P200

None P200 None P203 None P200 None P200

None P200

120 me P200

120 mf P003

None P200

120 m£ P200

None P200

120 mf P200

None P002 PP84

120 me P200

IMDG CODE (Amdt. 33-06)

Portable tanks and bulk containers EmS Stowage and segregation

IMO UN

tank tank instructions instructions

(12) (13) T50

T50 T75

TP91 T50

T50

Tl0

T50

Provisions

(14)

TP5

TP20 TP90

TP2

IMDG CODE (Amdt. 33-06)

(15) (16)

F-O, S-U Category D. Clear of living quarters.

F-O, S-U Category B. Clear of living quarters.

F-D, S-U Category D. Clear of living quarters.

F-D, S-U Category B. Clear of living quarters.

F-D, S-U Category D. Clear of living quarters.

F-D, S-U Category B. Clear of living quarters.

F-C, S-V Category E. Clear of living quarters.

F-C, S-V Category A

F-C, S-W Category D. Clear of living quarters. Segregation as for class 5.1 but "Separated from"

class 7.

F-C, S-V Category A

F-C, S-U Category O. Clear of living quarters.

F-D, S-U Category E. Clear of living quarters. "Separated from"

chlorine

F-C, S-U Category D. Clear of living quarters.

F-E, S-D Category D. Clear of living quarters.

F-C, S-U Category D. Clear of living quarters.

F-D, S-U Category D. Clear of living quarters.

F-D, S-U Category E. Clear of living quarters.

F-C, S-V Category A.

F-D, S-U Category B. Clear of living quarters.

F-C, S-V Category A

Chapter 3.2 - Dangerous Goods List

Properties and observations

(17)

UN No.

(18) Liquefied, flammable gas with an ammonia-like odour. 1036 Explosive limits: 3.5% to 14%. Heavier than air (1.6). Boiling point: 1

rc.

Liquefied, flammable gas. Explosive limits: 3.5% to 15%. Much 1037 heavier than air (2.2). Boiling point: 13"C.

Liquefied, flammable gas. Explosive limits: 3% to 34%. Lighter 1038 than air (0.98).

Liquefied, flammable gas. Explosive limits: 2% to 1 0%. Much 1 039 heavier than air (2.1). Boiling point: 11 "C.

Liquefied, flammable, toxic gases with an ether-like odour.

Heavier than air (1.5). Boiling point: 11°C.

1040

Liquefied, flammable gas with an ether-like odour. Heavierthan 1041 air (1.5).

Non-flammable aqueous solution of ammonium nitrate, calcium nitrate, urea and their mixtures containing ammonia gas. Emits toxic vapours of ammonia.

1043

Fire extinguishers, containing compressed or liquefied gases 1044 under pressure above 175 kPa for expelling fire-extinguishing contents.

Non-flammable, toxic and corrosive pale yellowish gas with a 1045 pungent odour. Poweriul oxidant which may cause fire. Reacts with water or moist air to produce toxic and corrosive fumes.

Corrosive to glass and to most metals. Will explode when mixed with hydrogen. Heavier than air (1.3). Highly irritating to skin, eyes and mucous membranes.

Inert gas. Much lighter than air (0.14). 1046 Non"flammable, toxic and corrosive gas with a pungent odour. 1048 Highly corrosive in the presence of water. Much heavier than air (3.6). Highly irritating to the skin, eyes and mucous membranes.

Flammable, odourless gas. Explosive limits: 4% to 75%. Much 1049 lighter than air (0.07).

Non-flammable, toxic and corrosive colourless gas with a 1050 pungent odour. Highly corrosive in the presence of water.

Heavier than air (1.3). Highly irritating to skin, eyes and mucous membranes.

Very volatile, colourless flammable liquid, evolving extremely 1051 toxic flammable vapours. Boiling point: 26"C.

Flashpoint: -18"C c.c. Miscible with water. Highly toxic if swallowed, by skin contact or by inhalation.

Colourless, fuming and highly volatile liquid with an irritating 1052 and pungent odour. Highly corrosive to metals and glass in the presence of moisture. Boiling point: 20°C. Toxic if swallowed, by skin contact or by inhalation. Causes severe burns to skin, eyes and mucous membranes.

Liquefied, flammable, toxic gas with a foul odour. Heavier than 1053 air (1.2).

Flammable hydrocarbon gas. Explosive limits: 1.8% to 8.8%. 1055 May contain propane, cyclopropane, propylene, butane,

butylene, etc., in varying proportions. Heavier than air (1.94).

Inert gas. Much heavier than air (2.9). 1056 Lighters or lighter refills containing butane or other flammable 1057 gas.

Non-flammable gases or mixtures of such gases which are 1058 used for filling receptables from which the contents are to be dispersed under pressure. Vapour may be heavier than air.

43 Part 3 - Dangerous Goods List and limited quantities exceptions

---.---.--.-.---~----.. - - - -.. ----"--".~-~--.. .---~--~ ---..

---UN Proper Shipping Name Class Subsidiary Packing Special Limited Packing IBC

No. (PSN) or risk(s) group provisions quantities Instruc- Provisions Instruc- Provisions

divi- tions tions

sion

(1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11)

1060 METHYLACETYLENE AND PROPADIENE 2.1 None P200

MIXTURE, STABILIZED

1061 METHYLAMINE, ANHYDROUS 2.1 None P200

1062 METHYL BROMIDE with not more than 2.3 23 None P200

2.0% chloropicrin

1063 METHYL CHLORIDE (REFRIGERANT GAS 2.1 None P200

R 40)

1064 METHYL MERCAPTAN 2.3 2.1 None P200

1065 NEON, COMPRESSED 2.2 120

me

^P200

1066 NITROGEN, COMPRESSED 2.2 120

me

^P200

1067 DINITROGEN TETROXIDE (NITROGEN 2.3 51/8 None P200

DIOXIDE)

1069 NITROSYL CHLORIDE 2.3 8 None P200

1070 NITROUS OXIDE 2.2 5.1 None P200

1071 OIL GAS, COMPRESSED 2.3 2.1 None P200

1072 OXYGEN,COMPRESSED 2.2 5.1 None P200

1073 OXYGEN, REFRIGERATED LIQUID 2.2 5.1 None P203

1075 PETROLEUM GASES, LIQUEFIED 21 None P200

•

1076 PHOSGENE 2.3 8 None P200

1077 PROPYLENE 2.1 None P200

1078 REFRIGERANT GAS, N.O.S. 2.2 274 120

me

^P200

•

1079 SULPHUR DIOXIDE 2.3 8 None P200

1080 SULPHUR HEXAFLUORIDE 2.2 120

me

^P200

1081 TETRAFLUOROETHYLENE, STABILIZED 2.1 None P200

1082 TRIFLUOROCHLOROETHYLENE, 2.3 2.1 None P200

STABILIZED

1083 TRIMETHYLAMINE, ANHYDROUS 2.1 None P200

44

IMDG CODE (Amdt. 33-06)

Portable tanks and bulk containers EmS Stowage and segregation

IMO UN

tank tank instructions instructions

(12) (13) TSO TSO TSO

TSO TSO

TSO

T7S TSO

TSO TSO TSO

TSO T50

Provisions

(14)

TP21

TPS TP22

TP19

IMDG CODE (Amdt. 33-06)

(15) (16)

F-O, SOU Category B. Clear of living quarters.

F-C, SOU Category O. Clear of living quarters.

F-O, SOU Category O. Clear of living quarters.

F-O, SOU Category D. Clear of living quarters.

F-C, S-V Category A.

F-C, SOW Category D. Clear of living quarters. Segregation as for class 5.1 but "Separated from"

class 7.

F-C, SOU Category O. Clear of living quarters.

F-C, SOW Category A. Clear of living quarters.

F-O, SOU Category O. Clear of living quarters.

F-C, SOW Category A.

F-C, SOW Category O.

F-O, SOU Category E. Clear of living quarters

F-C, SOU Category O. Clear of living quarters.

F-D, SOU Category E. Clear of living quarters.

F-C, S-V Category A.

F-C, SOU Category O. Clear of living quarters.

F-C, S-V Category A.

F-O, SOU Category E. Clear of living quarters.

F-O, SoU Category B. Clear of living quarters.

Chapter 3.2 - Dangerous Goods List

Properties and observations

(17)

Flammable gas. Explosive limits: 3% to 11 %. Heavier than air (1.4).

UN No.

(18)

Liquefied, flammable gas with an ammonia-like odour. Heavier 1061 than air (1.09).

Liquefied, toxic gas with a chloroform-like odour. Much heavier than air (3.3). Boiling point: 4.SoC. Even though this substance has a flammability hazard, it only exhibits such hazard under extreme fire conditions in confined areas.

Liquefied, flammable gas. Explosive limits: 8% to 20%. Heavier 1063 than air (1.8).

Liquefied, flammable, toxic gas with a foul odour. Heavier than air (1.7). Boiling point: 6°C.

Inert gas. Lighter than air (0.7). 1065

Non-flammable, odourless gas. Lighter than air (0.97).

Liquefied, non-flammable, toxic and corrosive gas which gives off brown vapours with a pungent odour. Strong oxidizing agent. Corrosive in the presence of water. Heavier than air (1.6). Boiling point: 21 "C. Highly irritating to skin, eyes and mucous membranes. Toxic by inhalation, with delayed effect, similar to phosgene.

Non-flammable, toxic yellow gas with an irritating odour. 1069 Corrosive to steel. Much heavier than air (2.3). Highly irritating to skin, eyes and mucous membranes.

Non-flammable gas. Strong oxidizing agent. Heavier than air 1070 (1.5).

Flammable, toxic gas. A mixture of hydrocarbons and carbon 1071 monoxide.

Non-flammable, odourless gas. Strong oxidizing agent. Heavier 1072 than air (1.1).

Liquefied, non-flammable gas Strong oxidizing agent. Mixtures 1073 of liquid oxygen with acetylene or oils may explode.

Flammable hydrocarbon gases or mixtures obtained from 1075 natural gas or by distillation of mineral oils or coal, etc. May contain propane, cyclopropane, propylene, butane, butylene, etc., in varying proportions. Heavier than air.

Liquefied, non-flammable, toxic and corrosive gas with a foul 1076 odour. Corrosive in the presence of water. Much heavier than air (3.5). Boiling point: SoC. Highly irritating to skin, eyes and mucous membranes. This gas is particularly dangerous in that it may be inhaled without immediate effect but can cause severe damage and death after a few hours' delay.

Flammable hydrocarbon gas. Explosive limits: 2% to 11.1 %. 1077 Heavier than air (I.S).

Different chlorofluorohydrocarbons or other non-flammable, 1078 non-toxic gases considered as refrigerant agents.

Non-flammable, toxic and corrosive gas with a pungent odour 1079 Much heavier than air (2.3). Highly irritating to skin, eyes and mucous membranes.

Liquefied, non-flammable, odourless gas. Much heavier than 1080 air (S.1).

Liquefied, flammable gas. Explosive limits: 11% to 60%. Much 1081 heavier than air (3.5). Irritating to skin, eyes and mucous

membranes.

Flammable, toxic, odourless gas. Explosive limits: 8.4°/r, to 3S.7%. Much heavier than air (4.0).

Liquefied, flammable gas with a fishy odour. Explosive limits: 2% to 12%. Much heavier than air (2.1). Boiling point: 3"C.

1082 1083

.~---.---... --.-... ---~~---...

44 Part 3 - Dangerous Goods List and limited quantities exceptions

UN No.

Proper Shipping Name (PSN)

(1) (2)

1085 VINYL BROMIDE, STABILIZED 1086 VINYL CHLORIDE, STABILIZED

1087 VINYL METHYL ETHER, STABILIZED

1088 ACETAL

1089 ACETALDEHYDE

1090 ACETONE (ACETONE SOLUTIONS)

1091 ACETONE OILS

1092 ACROLEIN, STABILIZED

1093 ACRYLONITRILE, STABILIZED

1098 ALLYL ALCOHOL

1099 ALLYL BROMIDE

11 00 ALLYL CHLORIDE

1104 AMYL ACETATES

1105 PENTANOLS

1106 AMYLAMINES

1107 AMYL CHLORIDES

Class or divi-sion (3)

2.1 2.1

2.1

3 6.1

6.1

3 3

Subsidiary risk(s)

(4)

6.1

6.1 p

6.1

Packing group

(5)

III

Special Limited provisions quantities

(6) (7)

None None None 1 f

None

1 t

e

None

5 f

e

223 5 f

e

223 5

e

1 jI

Packing Instruc- Provisions

lions

(8) (9)

P200

P200 P001

P001

P601

P001

P602

P001

POO1 LP01

POO1 POO1 LP01 POO1

P001

IBC Instruc- Provisions

lions

(10) (11)

IBC02

IBC03

IBC02

IBC03

IBC02

IBC03

IBC02

IMDG CODE (Amdt. 33-06)

Chapter 3.2 - Dangerous Goods List

~-~~---- • • __ ~ • • _ _ _ _ om_. ---.---...

-.--~.-Portable tanks and bulk containers EmS Stowage and segregation Properties and observations UN

IMO

UN

Provisions No.

tank tank instructions instructions

(12) (13) (14) (15) (16) (17) (18)

T50 F-O,8-U Category B. Clear of living Liquefied, flammable gas. Much heavier than air (3.7). 1085 quarters. Boiling point: 16"C.

T50 F-O,8-U Category B. Clear of living Liquefied, flammable gas. Explosive limits: 4%t031%. 1086 quarters. Much heavier than air (2.2).

T50 F-O,8-U Category B. Clear of living Liquefied, flammable gas. Explosive limits: 2.6% to 39%. 1087 quarters. Heavier than air (2.0). Boiling point: 6°C.

T3 T4 TP1 F-E,8-D Category E. Colourless, volatile liquid with an agreeable odour. 1088 Flashpoint: below -1snc c.c. Explosive limits:1.6 to 10.4%

Miscible with water.

T11 TP2 F-E,8-D Category E. Colourless liquid with a pungent, fruity odour.

TP7 Flashpoint: -2TC c.c. Explosive limits: 4% to 57%.

Boiling point: 21°C. Miscible with water. Harmful if swallowed or by inhalation.

T3 T4 TP1 F-E,8-D Category E Colourless, clear liquid, with a characteristic mint-like odour. 1090 Flashpoint: -20"C to -18'C c.c. Explosive limits: 2.5% to 13%.

Miscible with water.

T1 T4 TP1 F-E,8-D Category B. Light yellow to brownish, oily liquids. Flashpoint: _4°C to 1091

TP8 SoC c.c. Immiscible with water.

T10 T14 TP2 F-E,8-D Category D. Clear of living Colourless or yellow liquid with a most irritating odour. 1092 TP7 quarters. Flashpoint: -26"C c.c. Explosive limits: 2.8% to 31 %. Boiling TP13 point: 52"C. Miscible with water. Highly toxic if swallowed, by

skin contact or by inhalation.

T10 T14 TP2 F-E,8-D Category E. Clear of living Colourless, mobile liquid with a mild pungent odour. 1093 TP13 quarters. Flashpoint: _5°C c.c. Explosive limits: 3% to 17%. Partially

miscible with water. Toxic if swallowed, by skin contact or by inhalation. Practice has shown that this substance may leak from packagings that ordinarily are leakproof to other chemicals.

T10 T14 TP2 F-E,8-0 Category O. Clear of living Colourless liquid with a pungent mustard·like odour. 1098 TP13 quarters. Flashpoint: 21 "c c.c. Explosive limits: 2.5% to 18%. Miscible

with water. Highly toxic if swallowed, by skin contact or by inhalation.

T10 T14 TP2 F-E,8-0 Category B. Clear of living Colourless to light yellow liquid with an irritating odour. 1099 TP13 quarters. Flashpoint: -1 e,c c.c. Explosive limits: 4.4% to 7.3%.

Immiscible with water. Highly toxic If swallowed, by skin contact or by inhalation.

T10 T14 TP2 F-E,8-0 Category E. Clear of living Colourless liquid with an unpleasant pungent odour. 1100 TP13 quarters. Flashpoint: -29"C c.c. Explosive limits: 3.3% to 11.1 %.

Boiling point: 44"C. Immiscible with water. Toxic if swallowed, by skin contact or by inhalation.

T1 T2 TP1 F-E,8-0 Category A. Colourless liquids with a pear- or banana-like odour. 1104 norma/-AMYL ACETATE: flash point 25°C c.c.

secondary-AMYL ACETATE: flashpoint 32°C c.c.

Immiscible with water.

T1 T4 TP1 F-E,8-0 Category B. Colourless liquids with a strong odour. Immiscible with water. 1105

TP29 tertiary-AMYL ALCOHOL: flash point 19"C to 21 "C c.c.

T1 T2 TP1 F-E,8-0 Category A. 8ee entry above. Explosive limits: 1.2% to 10.5%. 1105 T1 T7 TP1 F-E,8-C Category B. Colourless, clear liquids. Explosive limits 2.2% to 22%, 1106

norma/-AMYLAMINE (1-PENTYLAMINE):

flashpoint 4"C c.c.tertiary-AMYLAMINE (3-PENTYLAMINE):

flashpoint 2"C c.c. Miscible with water. Harmful by inhalation.

Cause burns to skin, eyes and mucous membranes.

T1 T4 TP1 F-E,8-C Category A. 8ee entry above. However, irritating to skin, eyes and mucous 1106 membranes.

T1 T4 TP1 F-E,8-D Category B. Colourless or light brown liquids with an aromatic odour. 1107 n-Amyl chloride: Flashpoint: 11 "C. Explosive limits:

norma/-AMYL CHLORIDE 1.4% to 8.6%. Immiscible with water.

IMDG CODE

(Amdt. 33-06)

45 Part 3 - Dangerous Goods List and limited quantities exceptions

UN Proper Shipping Name Class Subsidiary Packing Special Limited

No. (PSN) or risk(s) group provisions quantities

divi-sion

(1 ) (2) (3) (4) (5) (6) (7)

1108 1-PENTENE (n-AMYLENE) 3

None

1109 AMYL FORMATES 3 III 5 f

1110 AMYL METHYL KETONE 3 III 5

t

1111 AMYL MERCAPTANS 3 1 P

1112 AMYL NITRATES 3 III 5 {I

1113 AMYL NITRITE 3 1 P

1114 BENZENE 3 1 ji

1120 BUTANOLS 3 1 (!

1120 BUTANOLS 3 III 223 5£

1123 BUTYL ACETATES 3 1 f

1123 BUTYL ACETATES 3 III 223 5

t

1125 BUTYLAMINE 3 8 1 f'

1126 1-BROMOBUTANE 3 1 f

1127 CHLOROBUTANES 3 1

e

1128 BUTYL FORMATE 3 1

e

46

Packing IBe

Instruc-tions

(8) POO1

P001 LP01

P001 LP01 P001

P001 LP01

P001

POO1 LP01 POO1

POO1

Provisions Instruc- Provisions tions

(9) (10) (11)

IBC03

IBC02

IBC03

IBC02

IBC03

IBC02

IBC03

IBC02

...•.•...•..

~~~~~~-IMDG CODE (Amdt. 33-06)

Trong tài liệu THE UNITED STATES OF AMERICA (Trang 64-77)